Local Charge Excesses in Metallic Alloys: a Local Field Coherent Potential Approximation Theory

Electronic structure calculations performed on very large supercells have shown that the local charge excesses in metallic alloys are related through simple linear relations to the local electrostatic field resulting from distribution of charges in the whole crystal. By including local external fields in the single site Coherent Potential Approximation theory, we develop a novel theoretical scheme in which the local charge excesses for random alloys can be obtained as the responses to local external fields. Our model maintains all the computational advantages of a single site theory but allows for full charge relaxation at the impurity sites. Through applications to CuPd and CuZn alloys, we find that, as a general rule, non linear charge rearrangements occur at the impurity site as a consequence of the complex phenomena related with the electronic screening of the external potential. This nothwithstanding, we observe that linear relations hold between charge excesses and external potentials, in quantitative agreement with the mentioned supercell calculations, and well beyond the limits of linearity for any other site property.Comment: 11 pages, 1 table, 7 figure

Multihierarchical electrodes based on titanate nanotubes and zinc oxide nanorods for photoelectrochemical water splitting

Studies involving water splitting to form hydrogen and oxygen have attracted attention because H2 is considered the fuel of the future. Photoelectrocatalysts have been widely used for this application, and several metal oxides can be applied as catalysts. Among them, we highlight zinc oxide nanorods (ZnONRs) and titanate nanotubes (TiNTs); however, their individual nanostructures exhibit disadvantages. For example, ZnONR shows rapid recombination of the photogenerated charges, and TiNT gives rise to randomly orientated films; these disadvantages limit their application as photoanodes. In this study, for the first time, we present a new class of multihierarchical electrodes based on TiNT-decorated ZnONR films that exhibited superior results to the individual species. The TiNTs are homogenously dispersed over the surface of the rods without forming agglomerates, giving rise to a heterojunction that exhibits lower recombination rates. It was found that the results are better when the contents of TiNT in the electrode are higher; thus, glycine was successfully used as a bridge to link both of the structures, increasing the amount of TiNT decorating the rods. As a result, the photocurrent generated with these multihierarchical electrodes is higher than that obtained for pure ZnONR electrodes (0.9 mA and 0.45 mA, respectively), and the electrode potentials for O2 evolution is lower than that observed for pure TiNT electrodes (0 V and 0.8 V vs. ERHE, respectively). The IPCE values are also higher for the multihierarchical electrodes

Transition from decelerated to accelerated cosmic expansion in braneworld universes

Braneworld theory provides a natural setting to treat, at a classical level, the cosmological effects of vacuum energy. Non-static extra dimensions can generally lead to a variable vacuum energy, which in turn may explain the present accelerated cosmic expansion. We concentrate our attention in models where the vacuum energy decreases as an inverse power law of the scale factor. These models agree with the observed accelerating universe, while fitting simultaneously the observational data for the density and deceleration parameter. The redshift at which the vacuum energy can start to dominate depends on the mass density of ordinary matter. For Omega = 0.3, the transition from decelerated to accelerated cosmic expansion occurs at z approx 0.48 +/- 0.20, which is compatible with SNe data. We set a lower bound on the deceleration parameter today, namely q > - 1 + 3 Omega/2, i.e., q > - 0.55 for Omega = 0.3. The future evolution of the universe crucially depends on the time when vacuum starts to dominate over ordinary matter. If it dominates only recently, at an epoch z < 0.64, then the universe is accelerating today and will continue that way forever. If vacuum dominates earlier, at z > 0.64, then the deceleration comes back and the universe recollapses at some point in the distant future. In the first case, quintessence and Cardassian expansion can be formally interpreted as the low energy limit of our model, although they are entirely different in philosophy. In the second case there is no correspondence between these models and ours.Comment: In V2 typos are corrected and one reference is added for section 1. To appear in General Relativity and Gravitatio

A 5D non compact and non Ricci flat Kaluza-Klein Cosmology

A model universe is proposed in the framework of 5-dimensional noncompact Kaluza-Klein cosmology which is not Ricci flat. The 4D part as the Robertson-Walker metric is coupled to conventional perfect fluid, and its extra-dimensional part is coupled to a dark pressure through a scalar field. It is shown that neither early inflation nor current acceleration of the 4D universe would happen if the non-vacuum states of the scalar field would contribute to 4D cosmology.Comment: 13 pages, major revision, published online in GR

Production and Clinical Evaluation of Norwalk GI.1 Virus Lot 001-09NV in Norovirus Vaccine Development

Background: Human noroviruses (HuNoV) are the leading cause of gastroenteritis. No vaccine is currently available to prevent norovirus illness or infection. Safe, infectious challenge strains are needed to assess vaccine efficacy in the controlled human infection model (CHIM). Methods: A stock of HuNoV strain Norwalk virus ([NV] GI.1) was prepared. Healthy, genetically susceptible adults were inoculated with NV Lot 001-09NV and monitored for infection, gastroenteritis symptoms, and immune responses. Results: Lot 001-09NV induced gastroenteritis in 9 (56%) and infection in 11 (69%) of 16 genetically susceptible subjects. All infected subjects developed strong immune responses to GI.1 with a 30-fold (geometric mean titer) increase in blocking titers (BT50) and a 161-fold increase in GI.1-specific immunoglobulin (Ig)G titers when compared with baseline. GI.1-specific cellular responses in peripheral blood were observed 9 days postchallenge with an average of 3253 IgA and 1227 IgG antibody-secreting cells per million peripheral blood mononuclear cells. Conclusions: GI.1 Lot 001-09NV appears to be similar in virulence to previous passages of NV strain 8fIIa. The safety profile, attack rate, and duration of illness make GI.1 Lot 001-09NV a useful challenge strain for future vaccine studies aimed at establishing immune correlates

Association of polymorphisms in genes encoding hormone receptors ESR1, ESR2 and LHCGR with the risk and clinical features of testicular germ cell cancer.

Testicular germ cell cancer (TGCC) is the most common malignancy in young men. Genetic variants known to be associated with risk of TGCC only partially account for the observed familial risks. We aimed to identify additional polymorphisms associated with risk as well as histological and clinical features of TGCC in 367 patients and 214 controls. Polymorphisms in ESR2 (rs1256063; OR=0.53, 95% CI: 0.35-0.79) and LHCGR (rs4597581; OR=0.68, 95% CI: 0.51-0.89, and rs4953617; OR=1.88, 95% CI: 1.21-2.94) associated with risk of TGCC. Polymorphisms in ESR1 (rs9397080; OR=1.85, 95% CI: 1.18-2.91) and LHCGR (rs7371084; OR=2.37, 95% CI: 1.26-4.49) associated with risk of seminoma and metastasis, respectively. SNPs in ESR1 (rs9397080) and LHCGR (rs7371084) were predictors of higher LH levels and higher androgen sensitivity index in healthy subjects. The results suggest that polymorphisms in ESR1, ESR2 and LHCGR contribute to the risk of developing TGCC, histological subtype, and risk to metastasis

Algebraic Attack against Variants of McEliece with Goppa Polynomial of a Special Form

International audienceIn this paper, we present a new algebraic attack against some special cases of Wild McEliece Incognito, a generalization of the original McEliece cryptosystem. This attack does not threaten the original McEliece cryptosystem. We prove that recovering the secret key for such schemes is equivalent to solving a system of polynomial equations whose solutions have the structure of a usual vector space. Consequently, to recover a basis of this vector space, we can greatly reduce the number of variables in the corresponding algebraic system. From these solutions, we can then deduce the basis of a GRS code. Finally, the last step of the cryptanalysis of those schemes corresponds to attacking a McEliece scheme instantiated with particular GRS codes (with a polynomial relation between the support and the multipliers) which can be done in polynomial-time thanks to a variant of the Sidelnikov-Shestakov attack. For Wild McEliece & Incognito, we also show that solving the corresponding algebraic system is notably easier in the case of a non-prime base eld Fq. To support our theoretical results, we have been able to practically break several parameters de ned over a non-prime base field q in {9; 16; 25; 27; 32}, t < 7, extension degrees m in {2,3}, security level up to 2^129 against information set decoding in few minutes or hours

An overview of the MHONGOOSE survey: Observing nearby galaxies with MeerKAT

MHONGOOSE is a deep survey of the neutral hydrogen distribution in a representative sample of 30 nearby disk and dwarf galaxies with HI masses from 10^6 to ~10^{11} M_sun, and luminosities from M_R ~ -12 to M_R ~ -22. The sample is selected to uniformly cover the available range in log(M_HI). Our extremely deep observations, down to HI column density limits of well below 10^{18} cm^{-2} - or a few hundred times fainter than the typical HI disks in galaxies - will directly detect the effects of cold accretion from the intergalactic medium and the links with the cosmic web. These observations will be the first ever to probe the very low-column density neutral gas in galaxies at these high resolutions. Combination with data at other wavelengths, most of it already available, will enable accurate modelling of the properties and evolution of the mass components in these galaxies and link these with the effects of environment, dark matter distribution, and other fundamental properties such as halo mass and angular momentum. MHONGOOSE can already start addressing some of the SKA-1 science goals and will provide a comprehensive inventory of the processes driving the transformation and evolution of galaxies in the nearby universe at high resolution and over 5 orders of magnitude in column density. It will be a Nearby Galaxies Legacy Survey that will be unsurpassed until the advent of the SKA, and can serve as a highly visible, lasting statement of MeerKAT's capabilities

Dynamics of Modified Chaplygin Gas in Brane World Scenario: Phase Plane Analysis

In this work we investigate the background dynamics when dark energy is coupled to dark matter with a suitable interaction in the universe described by brane cosmology. Here DGP and the RSII brane models have been considered separately. Dark energy in the form of modified Chaplygin gas is considered. A suitable interaction between dark energy and dark matter is considered in order to at least alleviate (if not solve) the cosmic coincidence problem. The dynamical system of equations is solved numerically and a stable scaling solution is obtained. A significant attempt towards the solution of the cosmic coincidence problem is taken. The statefinder parameters are also calculated to classify the dark energy models. Graphs and phase diagrams are drawn to study the variations of these parameters. It is also seen that the background dynamics of modified Chaplygin gas is completely consistent with the notion of an accelerated expansion in the late universe. Finally, it has been shown that the universe in both the models follows the power law form of expansion around the critical point, which is consistent with the known results.Comment: 14 pages, 14 figure

Dynamics of Interacting Generalized Cosmic Chaplygin gas in Brane-world scenario

In this work we explore the background dynamics when dark energy is coupled to dark matter with a suitable interaction in the universe described by brane cosmology. Here DGP and the RSII brane models have been considered separately. Dark energy in the form of Generalized Cosmic Chaplygin gas is considered. A suitable interaction between dark energy and dark matter is considered in order to at least alleviate (if not solve) the cosmic coincidence problem. The dynamical system of equations is solved numerically and a stable scaling solution is obtained. A significant attempt towards the solution of the cosmic coincidence problem is taken. The statefinder parameters are also calculated to classify the dark energy models. Graphs and phase diagrams are drawn to study the variations of these parameters. It is also seen that the background dynamics of Generalized Cosmic Chaplygin gas is consistent with the late cosmic acceleration, but not without satisfying certain conditions. It has been shown that the universe in both the models follows the power law form of expansion around the critical point, which is consistent with the known results. Future singularities were studied and our models were declared totally free from any types of such singularities. Finally, some cosmographic parameters were also briefly studied. Our investigation led to the fact that although GCCG with a far lesser negative pressure compared to other DE models, can overcome the relatively weaker gravity of RS II brane, with the help of the negative brane tension, yet for the DGP brane model with much higher gravitation, the incompetency of GCCG is exposed, and it cannot produce the accelerating scenario until it reaches the phantom era.Comment: 34 pages, 30 figures. arXiv admin note: substantial text overlap with arXiv:1204.3531, arXiv:1109.1481, arXiv:1109.357